ASHRAE 34 REFRIGERANT DESIGNATION

ASHRAE 34 is a standard which used to common the refrigerants naming instead of using different type of chemical names, formula, and etc. It consists uniform refrigerant designation numbering, safety classification, refrigerant concentration limits (RCL) to refrigerant, and application of new refrigerants. An identifying number shall be assigned to each refrigerant. Speaking of refrigerant designation numbers, let's split into two sections: prefix and suffix.

Prefix

Prefix consists of both technical and non-technical designations are explained in the following Both technical and non-technical designations are explained in the following:

1. Technical

  • The identifying number shall be preceded by the letter “R”, the word “Refrigerant”. For example, R410A, R-410A, Refrigerant 410A. They are allowed to use in technical publication, equipment nameplates and product specification.
  • The identifying number shall be preceded by the manufacturer’s trademark or trade name. For example, [Trade Name] 12, [Trade Name] R 12. It can be used in technical publication.

2. Non Technical

  • The identifying number shall be prefixed with:
    i. First letter: H to signify that the compounds contain hydrogen
    ii. Second letter: B, C, F or I or a combination thereof in this sequence to signify the presence of bromine, chlorine, fluorine or iodine respectively.
    iii. Third letter: C for carbon
    For example: HCFC (hydrochlorofluorocarbon)
  • The ether shall substitute an “E” for “C” (carbon).
    For example: HCFE (hydrochlorofluoroethers)
  • The halogenated olefins shall be either:
    i. HCFC or
    ii. Substitution of “o” for the carbon “C”
    For example: HCFC (hydrochlorofluorocarbon) or HCFO
  • Blends can be identified using appropriate composition designation prefixed for each component.
    HCFC-22/HFC-152a/CFC-114

Suffix

1. Suffix for saturated hydrocarbons

Example 1: R 134a (CH2FCF3)

Titles Designation numbers Explanation
Prefix R Refrigerant
First digit 1 One less than the carbon atom: C – 1
CH2FCF3 : First digit = 2 – 1 = 1
Second digit 3 One more than the hydrogen atom: H + 1
CH2FCF3: Second digit =2 + 1 = 3
Third digit 4 Number of fluorine atoms
CH2FCF3 = 4
Alphabet a Lowercase letter represent isomers


Example 2: R 12B1 (CBrClF2)

Titles Designation numbers Explanation
Prefix R Refrigerant
First digit 0 One less than the carbon atom: C – 1
CBrClF2 : First digit = 1 – 1 = 0
Second digit 1 One more than the hydrogen atom: H + 1
CBrClF2: Second digit = 0 + 1 = 1
Third digit 2 Number of fluorine atoms
CBrClF2 = 2
- B1 If bromine (Br) is present in place of part or all of the chlorine, the same rules as above apply, except that the uppercase letter “B” after the designation for the parent chlorofluoro compound shows the presence of bromine. The number following the “B” shows the number of bromine atoms present
Number of bromine atoms:
CBrClF2 = B1
* same case if iodine (I) is present.


Note: The number of chlorine atoms in the compound is found by subtracting the sum of fluorine (F), bromine (Br), iodine (I), and hydrogen atoms from the total number of atoms that can be connected to the carbon (C) atoms. Number of carbon atom for saturated refrigerant: 2n + 2, where n is the number of carbon atoms

2. Suffix for unsaturated hydrocarbons

Example: R 1150 (CH2=CH2)

Titles Designation numbers Explanation
Prefix R Refrigerant
First digit 1 Number of double or triple bonds
CH2= CH2: Double bond = 1
Second digit 1 One less than the carbon atom: C – 1
CH2=CH2 : Second digit = 2 – 1 = 1
Third digit 5 One more than the hydrogen atom: H + 1
CH2=CH2: Third digit = 4 + 1 = 5
Fourth digit 0 Number of fluorine atoms:
0



3. Suffix for zeotropic blends (400 series)

Example: R410A (R32/R125)

Titles Designation numbers Explanation
Prefix R Refrigerant
First digit 410 Zeotropic blends shall be assigned an identifying number in the 400 series. It is based on the sequence of new applied refrigerant. First refrigerant that applied in ASHRAE 34 named as R401 and therefore continue with 402, 403, and etc.
Alphabet A Uppercase letter: To differentiate among blends having the same components with different proportions (% m/m), an uppercase shall be added as a suffix in serial order of assignment.


4. Suffix for azeotropes blends (500 series)

Example: R505 (R12/R31)

Titles Designation numbers Explanation
Prefix R Refrigerant
Digits 505 Azeotropic blends shall be assigned an identifying number in the 500 series. First refrigerant that applied in ASHRAE 34 named as R501 and therefore continue with 502, 503, and etc.


5. Suffix for miscellaneous organic compounds (600 series)

Example 1: CH3CH2CH2CH2CH3 R601 (hydrocarbon only)

Titles Designation numbers Explanation
Prefix R Refrigerant
Digits 601 Miscellaneous organic compounds shall be assigned in the 600 series.
CH3CH2CH2CH2CH3 (saturated hydrocarbon):
600 + (Carbon – 4) = 600 + (5-4) = 601


Example 2: R610 (oxygen compound)

Titles Designation numbers Explanation
Prefix R Refrigerant
Digits 610 Miscellaneous organic compounds shall be assigned in the 600 series in decadal groups.
Hence, oxygen compounds can start from 610 series.
Sulfur compounds start from 620 series.
Nitrogen compounds start from 630 series.


6. Suffix for inorganic compounds (700 and 7000 series)

Example: R717 (ammonia)

Titles Designation numbers Explanation
Prefix R Refrigerant
Digits 717 Inorganic compounds shall be assigned numbers in the 700.
Ammonia relative molecular mass = 17g/mol
700 + 17 = 717
Note: For 7000 series, in case the relative molecular mass more than 100g/mol.


                               

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